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Materiale Plastice
https://doi.org/10.37358/Mat.Plast.1964

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ISSN 0025-5289
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Materiale Plastice, Volume 47, Issue 1, pp. (2010)




Ana-Maria Pana, Lucian-Mircea Rusnac, Geza Bandur, Eugen Sisu, Valentin Badea, Mihaela Silion Synthesis and Characterization of New Glycopolymers based on Monosaccharides and Maleic Anhydride. I. Glucose derivatives


Abstract:
Polymers become more important in everyday life. Although extremely useful in their life cycle, polymers become long-term pollutants. Worldwide, along the increased research in the environmental field, one can obviously observe a keen interest into new biodegradable and biocompatible plastic materials. This paper presents the synthesis and characterization of a new class of biodegradable copolymers based on carbohydrates. An oligomer was synthesized by the polycondensation of 3-benzyl-5,6-(bis(maleyloxy))-1,2-isopropylideneglucofuranose with propane-1,3-diol in the presence of p-toluenesulfonic acid and then it was copolymerized with hydroxypropyl (meth)acrylate, using benzoyl peroxide as initiator. The oligomer was characterized by FTIR, NMR spectroscopy and HPLC-MS, and the copolymers were analyzed using FTIR and thermogravimetry. Keywords: glucose, glycopolymer, maleic anhydride



Issue: 2010 Volume 47, Number 1
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